Showing posts with label Anionic. Show all posts
Showing posts with label Anionic. Show all posts

Cationic Starch - Technical paper making


Cat-ionic Starch - Technical paper making


Starch is used to increase the strength properties of paper and improve the sizing by means of coating the sheet with starch slurry or adding starch at the wet end of the machine.

Starch much like cellulose is a chain made up of glucose molecules, bridged together by oxygen atoms called “glycosides”. This makes starch very soluble in water but also easily digestible by bacteria.

There are two types of starch used in paper making, Cat-ionic wet end starch, and oxidized starch.

Wetend Starch Cookers (Cationic maize starch)

Wetend starch is modified using a derivatized quaternary ammonium compound to add a cat-ionic charge to the starch. This allows the starch to naturally bond with the anionic fibers, Fillers and fines (all anionic).
In a way cat-ionic starch can help improve drainage as well as improving dry strength properties in the sheet.

Cat-ionic starch can be added to different locations in the machine approach flow or Thick stock loop. Dosing in different locations can influence the advantages you get from cat-ionic starch.

Adding starch to the Pulp storage chest of the machine acts like a Fixative. The cat-ionic starch binds to the anionic trash in the pulp, cleaning the water loop, improving Wetend retention and in some cases acts like a dry strength agent.

For the strength impact cat-ionic starch should be dosed close to the thick stock pump. The short dwell time prevent the starch from attracting only the anionic trash. The starch can form bridges between the fibres fillers and fines to create a stronger better formation sheet as well as  improving formation. 

Uncooked cat-ionic starch can be added between the layers of a multi ply machine. The starch is sandwiched between the ply’s. Its not until the sheet is passed through the drying section that the starch cooks and acts like an inter layer glue. This can be important if the paper has a specific ply bond strength parameter that needs to be adhered to.

Papermachine Cleaning Chemicals - Technical Papermaking

Wire conditioner

Wire conditioner is sprayed on to the wires of the fourdrinier machine. The job of the wire conditioner is to coat the wire and prevent stickie’s, glues, pitch and other tacky substances from binding with the wire plugging the holes in the mesh. Blocked parts on the wire will inhibit drainage leading to weight and moisture deviations as well as holes/ weak spots in the sheet. these will cause a lot of issues on the paper machine.

When problems occur on the paper machines wire like marks from stickie’s and hot melts a caustic chemical clean on the headbox can remove the hot melts. Caustic soda is used because it breaks down inorganic materials like chalk, ash and stickie’s.

Felt conditioner

Felt conditioner works in a similar way to the wire conditioner helps prevents stickie’s and pitch from attaching to the felt and blocking the felt. An excessive amount of pitch on the felts not only hinders dewatering but sticks off a small amount of fibers. After time this will build up and cause defects in the sheet, potentially leading to breaks.

Chemical felt cleaning and conditioning

Chemical precipitates found in the press section are inorganic as well as organic. The organic or hydrophobic types include rosin size, wet strength resin, and pitch and hydrocarbon oil. Inorganic precipitates include clay, calcium carbonate.  
Generally speaking, chemicals for cleaning felts are applied using either a continuous or a shutdown cleaning method. Continuous cleaning effectively keeps the felt open during its run rather than relying on the more difficult job of cleaning a plugged felt.

Chemical felt washes are done more infrequently on PM3/6 than on PM4, usually if the machine has been shut for a while a chemical wash is usually done but on crawl speed to allow better penetration of the chemicals in the felt. Using a lower speed allows the chemicals to bed in and reacts with the dirt and contaminates.

 Acid

Acid is used in two ways on the machines, continuously dosing and shock dosing. The acid is used continuously on all of the machines to help keep the felt open, rather than relying on the shock cleaning on a closed felt.
The Shock dosing is done at a high concentration of acid, it is important to ensure the water is running, neat acid will melt the felts.

Acid is used to clean the felts and to neutralise the caustic that has been previously dosed. The acid is dosed through the chemical sprays on the felts. Acid is dosed for ten mins with 5 mins flushing time after. The acid removes the broken down pitch, fines etc. in the felts. The acid is delivered in a higher concentration when shock dosed and more dilution water is added when the acid is used continuously to keep the felts cleaned. The caustic id a alkaline which is on the opposite spectrum to the acid.

Caustic Soda

Caustic is used to treat the felts. The chemical is shock dosed through the chemical sprays onto the felts to break up the pitch, ash, fines and dirt collected in the felts. The caustic is applied for 10 mins on each of the felts. The issue with caustic being used on the felts is the chemical can cause the felt to close up, reducing the efficient of water removal. After the chemical dosing the lines are flushed with fresh water to clean the pipe work and sprays.

 Anti-Scale Chemical

Anti-Scale chemical is important chemical because the papermaking process is water based. Scale is made up of minerals (mainly chalk and limestoneare composed mainly of calcium carbonate (CaCO3), magnesium hydroxide (Mg(OH)2), and calcium sulfate (CaSO4)) within the water precipitating out and building up within water systems.

Industrial water systems using hard water can experience breakdowns as the scale builds up in pipes, boilers, water tanks etc. To maintain the level of scale within the water systems a chemical is doses at specific points to dissolve/ break down the chalky deposits preventing build up and ultimately costly breakdowns.

The effects of scale

Can restrict the flow through pipes as the internal diameter decreases as the scale builds up in the pipe.
Scale impairs the heat exchange between metals into the water. this reduces the cooling/ heating efficiency and can lead to the metal components over heating. This causes issues with the drying cylinders requiring more steam to dry the paper because not al heat can be transferred through the cylinder if a build up of scale occurs.


Below is a list of all the dosing points in the site. There are problematic areas that scale is likely to build up and can cause catastrophic breakdowns for example. If the dosing to the pump seal water failed the pumps can clog up with scale, pumping would be reduced and the mechanical could seize. 

Bentonite addition - Technical Papermaking

Bentonite (anionic smectite clay)

Bentonite is the name given to the anionic smectite clay material used to improve retention and drainage. The composition of the particles can be described as very thin plates caused by the salts in the clay. This gives a large surface area for the particle to bond with other particles and cationic polymer.

The bentonite has two functions, primarily when use either before or after a cationic polymer it serves as a drainage/ retention aid. When bentonite is used with cationic polymer it can be used to control the level of pitch, tacky materials (commonly referred to as Anionic trash).

Bentonite added down-stream to polymer improves dewatering on the wire. Best achieved when high mass cationic polymer is used has been added so that the stock furnish has a momentary net cationic charge. If the stock has a high level of Anionic trash it makes sense to firstly treat the stock with sufficient cationic polymer.

Bentonite works with the polymer to increase the dewatering capabilities of the paper web, the two chemicals work in unison to achieve this. Bentonite works as a drainage aid allowing the water to be removed more easily from the web. When adjusting the chemicals the set points of both the polymer and the hydrocol must be reduced or increased together, having a high polymer dosage and low hydrocol dosage or vice versa for example can decrease the drainage on the machine and cause poor formation.

Diluted Bentonite is added post screen and works by reforming the fiber flocculation’s that have been broken down  by shear forces going through the primary machine screen. Bentonite brings the smaller flocs together for better formation on the fourdrinier.