Cationic Starch - Technical paper making

Cat-ionic Starch - Technical paper making

Starch is used to increase the strength properties of paper and improve the sizing by means of coating the sheet with starch slurry or adding starch at the wet end of the machine.

Starch much like cellulose is a chain made up of glucose molecules, bridged together by oxygen atoms called “glycosides”. This makes starch very soluble in water but also easily digestible by bacteria.

There are two types of starch used in paper making, Cat-ionic wet end starch, and oxidized starch.

Wetend Starch Cookers (Cationic maize starch)

Wetend starch is modified using a derivatized quaternary ammonium compound to add a cat-ionic charge to the starch. This allows the starch to naturally bond with the anionic fibers, Fillers and fines (all anionic).

In a way cat-ionic starch can help improve drainage as well as improving dry strength properties in the sheet.

Cat-ionic starch can be added to different locations in the machine approach flow or Thick stock loop. Dosing in different locations can influence the advantages you get from cat-ionic starch.

Adding starch to the Pulp storage chest of the machine acts like a Fixative. The cat-ionic starch binds to the anionic trash in the pulp, cleaning the water loop, improving Wetend retention and in some cases acts like a dry strength agent.

For the strength impact cat-ionic starch should be dosed close to the thick stock pump. The short dwell time prevent the starch from attracting only the anionic trash. The starch can form bridges between the fibres fillers and fines to create a stronger better formation sheet as well as  improving formation. 

Uncooked cat-ionic starch can be added between the layers of a multi ply machine. The starch is sandwiched between the ply’s. Its not until the sheet is passed through the drying section that the starch cooks and acts like an inter layer glue. This can be important if the paper has a specific ply bond strength parameter that needs to be adhered to.

Starch Cooking - Technical Papermaking

Starch cooking techniques

Starch Addition – Solids content and Viscosity

Starch is mixed up and cooked to specification according to two specific parameters, the solids content of the final starch slurry and the final slurry’s viscosity.

The viscosity of the starch slurry increases exponentially as the cooked solids content increases. Even at low solids content the starch can be too thick to use efficiently. Therefore reagent is added (ammonium persulphate); this chemical reduces the viscosity of the slurry and allows for higher solids content. The reagent works by breaking down the long starch glucose chains into smaller chains this in turn reduces the viscosity. To stop the reduction, the starch is cooked again at a higher temperature to burn off the chemical.

a Pond starch press is designed to work between 40 – 70 cP viscosity (60 Deg C Spindle 62). Too high viscosity can cause a number of issues at the size press. Thicker starch slurry will not penetrate the sheet as efficiently. The starch as a result coats the paper and forces itself between the size press rolls and the sheet causing wear on the rubber rolls. Increasing the moisture of the sheet entering the size press will allow more starch to penetrate but at a cost of web strength through and especially after the press.

Thermoconversion of starch 

An older crude method of converting Starch molecule is Thermo-conversion. Once uncooked starch granules are mixed into a slurry. A reactant is added to the starch slurry to begin the cooking process. Ammonium Persulphate is the reaction chemical added to the starch. The starch and the ammonium persulphate is heated to 145 degrees to start the reaction. The ammonium persulphate breaks down the glucose chains reducing the overall viscosity of the starch.

The positive of thermochemical conversion is the robustness of the process. The system can withstand process variations more so than enzymatic conversion. For example changes in PH value or variations of starches being used. Enzymatic conversion has a tight tolerance on its process, if the pH value goes too acidic or alkali the enzyme will not function. Enzymatic conversion works best with a consistent process and limited variations.

Enzymatic conversion of starch

Enzymatic conversion of starch involves using an enzyme within the starch cooking process to break down the starch glucose chains allows for a reduction in the starch viscosity while being able to increase the starch solids. Without pre-treatment cooking, as the starch solids increase the viscosity increases in an exponential manner. The viscosity of the starch at the desired solid content would be unusable at a size press.

The cost benefits of using an enzyme would be being able to use a cheaper un-modified wheat starch rather than a modified starch. It also allows for more control on the degree of conversion, the starch chain length and the solid content can almost be tailored made depending on the enzyme dosing.

The Enzyme is dosed with the starch slurry and heated up to around 80 (75 for pm6) Deg C to kick-start the reaction. As the starch goes through the reaction tubes the starch chains break down. The mixture is the flash-heated with steam to 130 Deg C to stop the reaction. If this step did not occur the starch would break down to glucose sugars which have no strength additives.

Using the Enzyme cooking technique allows for higher solid content at a lower viscosity when compared with Thermoconversion of starch resulting in a higher strength gain in the sheet. 

Enzymatic conversion has much lower power consumption when compared to the thermochemical cooking process. The temperature needed for the cook is much lower (80 Deg C). The cookers use a flash cooker method to kill the enzyme. A flash cooker allows hot steam to kill of the enzyme without having to heat the entire mixture up.

Starch retrogression (Papermakers amylose)

Starch retrogression or “amylose crystallization” is a result of the re-association (chains link back together) of linear amylose or straight-chain fragments and amylopectin branched fragments. This is an issue that can occur within starch cooking systems. Papermaker’s amylose can lead to a number of paper making problems including hard drying, picking, dusting, low porosity, and a weak sheet.

Size Press's - Papermaking process overview

Papermaking process overview

Size press section

The role of the size press in a paper machine is to apply a thin layer of starch and or other chemicals to the paper web.

A typical starch press comprises two rolls with a starch application system to coat the rolls.

Starch addition can improve several paper properties for example;

• reduce dusting of the sheet or sealing lose material to the sheet
• increase in paper stiffness
• increase in burst strength property
• increase in short span compression (SCT)
• reduction in air permeability. 

Starch or size being added at the press has 100% retention. This is higher than applying the chemicals at the wet end. The retention rate would be roughly the same as the fiber retention (80%). More starch can be added at the size press compared to applying it using cationic starch.

Although not all the starch is absorbed in the pond/ addition point, the excess starch/ chemicals are recirculated back to the starch storage tank by the machine To be reused. 

There are typically two different size press designs, Pond size press (also known as a Size press) and Sym sizers. The basic principle is the same the only difference is the application to the sheet.

Sym sizers

These are cleaner than the pond method and are more suited for certain types of paper and certain strength properties that want to be achieved. Sym sizers consist of two rolls with the paper being fed between them. Both sets of rolls need to run at a matching speed to prevent skidding and possibly breaking the paper.

Applicators on either side of the rolls apply starch to a thin metal rod with a tapered edge. The roll then applied a specified amount of start to the larger roll which presses the starch onto the paper as it passes through. This creates a film of starch on the paper. The other advantage of this than the pond method would be the sheet doesn’t get as saturated with starch and takes less drying time after the size press (20% moisture leaving)

This method is used on lightweight grades of paper and paper that need a better burst strength and tensile strength (paper liners)

Pond Sizers

pond style size press is an older designed surface size coaters. Similar to the Sym sizers but instead of an applicator adding a thin layer to the role the starch is filled in the spaces between the roll and where the paper enters the nip.
The paper will become more saturated but greater strength can be achieved. Pond Size press allows starch to further penetrate the sheet compared to a Sym sizer This also means the paper is wetter when leaving the Size press (30% moisture)

Size Press Advantages to paper machine

Dusting reduction

Dust/ lint is produced from the paper when small particles become loose from the sheet and “picked out” from the hot cylinders. Sometimes dust is transferred onto the paper surface from rolls or fabrics, so it makes sense to inspect the surfaces in the wet-press, dryer, and calendar sections of the paper machine. Tacky materials in the wet-press area or on the early dryer cans sometimes pull fibers and other solid materials from the sheet, and these materials can appear later as dust.

Starch is a tacky substance and when applied to the paper web can be used to “stick down” loose materials in the sheet. On the other side of this depending on the dryers set up the starch can aid in pick outs from making the web tacky. 

Process Level Indicators - Papermachine Automation

Level Indicators

Load cells

A load cell is a transducer which emits an electrical signal when a load is applied. The electrical signal is proportional to the force being applied. Strain gauge load cells work in a similar way to the paddle consistency meters. The electrical signal can be calibrated to measure the weight/ fill capacity of a tank or hopper. Some starch mixing tanks, for example, use load cells to weigh the amount of starch for each batch.

The downside to load cells are, they have to be mounted in such a way that all of the weight/ load is on the load cell. The load cell can become deformed/ inaccurate if the transmitter is overloaded and as such fail-safes have to be fitted to prevent overloads. After a time the load cell loses its accuracy due to constant deformation of the transducer. Compared with the ultrasonic level transmitter the operating range is low.

Ultrasonic level transmitter

An ultrasonic transmitter uses ultra-sonic radio waves to determine the fill level in a tank. The transmitter sends out a signal. The signal hits the top of the liquid in the tank, reflects back to the transmitter where the time taken is calculated. The time is compared with the time calibrated when the tank was empty. A percentage can be calculated and this is the level of the tank. For example

If the tank, when empty took 5 mili seconds to send and receive the signal, at 50% fill volume the transmitter would record a 2.5 mili second delay.

Ultrasonic transmitters have a high rate of accuracy and tend to maintain their calibration over time. The transmitter can work on lower ranges than load cell transmitters. 

The disadvantage of ultrasonic transmitters can be the substance you're trying to measure, for example in a starch silo lots of dust is produced when filling. this dust can obstruct the ultrasonic transmitter giving a false or erratic reading

Guided wave radar

fundamentals of guided wave radar level measurement come directly from Time Domain Reflectometry (TDR), a technology that has been employed for decades to find breaks in underground cables and in-wall cable installations in large buildings. TDR instruments launch low amplitude, high-frequency pulses onto the transmission line, cable, or waveguide under test, and then sequentially sample the reflected signal amplitudes.

Guided wave Transmitters work on a similar principle as ultrasonic transmitters. the only difference is how the wave is emitted. the radar wave is sent through a "cable probe" that spans the height of the tank for example. the radar wave travels down the cable and reflects back. the transmitter uses time of flight principle to calculate a level. 
the pulses traveling through the probe are disturbed by the liquid or dry powder medium and reflects the signal back early giving a level reading.

Hydrostatic Transmitters

Hydrostatic transmitters are similar construction to pressure transmitters. the transmitter design is the same the application and calculations behind the transmitter vary. Placed at the 0 level of a tank or silo the hydrostatic transmitter will measure a hydrostatic head or "total head pressure" which is basically the pressure exerted by the water column in the tank. 

So, the filling height is calculated from the distance of the medium surface to the measuring point by the pressure measurement. The weight force of the liquid column, thus the hydrostatic pressure, however, is not only directly proportional to the filling height but also varies with the specific gravity of the medium and the force of gravity.

Stone Ground wood Pulp - Mechanical Pulp Production

Mechanical Wood Pulping

All mechanical wood pulping makes no attempt to remove an impurity known as lignin from the fibers. A product made from mechanical wood pulp will not be durable and will degrade rapidly especially in the sunlight.

Stone ground wood Pulp

This is the most commonly used method mainly due to the simplicity of the machine. one large grindstone which breaks up the descending log into individual fibers and fiber bundles.

Mechanical pulp is produced from fiber defibrillations from a stone grindstone. the temperature around of the pulp is around 80 to 125 deg, locally at the stone where the fibers are being broken down the temperatures can reach up to 170 deg.

this high temperature is an advantage because the lignin in the logs binding the fibers together starts to become more malleable allowing for less damage to the fibers, more intact fibers are produced. 

Thermo-ground wood pulp

The thermo-ground wood mechanical pulp is an advance on the stone groundwood process where the logs are treated with hot water. the logs sit above the stone grinder in a hot water bath. the hot water is used to make the lignin softer. when the lignin becomes soft the break down of the logs into fibers becomes easier leading to less energy being needed and higher quality pulp.
Temperature around 80 to 95 can be generated locally at the grindstone. The water temperature is usually around 80 deg C. 

Pressurized groundwood

This is another advance on the original stone groundwood pulp. this is mechanical pulp production where the grinding takes place under compresses air pressure usually about 1 bar above atmospheric pressure. the water pressure is there for greater than 95 deg C (due to high-pressure atmosphere raises the boiling point of water). this allows for higher grinding temperatures without steam flashing. the high temperature promotes the softening of lignin. this improves fiber separation and reduces the specific energy consumption of the pulp.
Grindstone temp is about 124 – 130 deg.

Basic principles – Stone groundwood process

The fibers are torn from the logs and washed from the stone by means of spray showers. The supply of fibers and fiber fragments go through a screening process to remove the large particles these are known as shives. The stock is then thickened.

At grinding the logs are heated up from the frictions of the grind stone caused by pressing the logs against the stone the wooden structure is softened, the lignin becomes more malleable when heated. The bonding between the fibers will be less. The shearing forces between the stone surface and the wood mean the fibers are torn out.

This process uses very little or no chemicals but is very energy intensive (1200 – 2100kw/ dry ton)

Under the pulp stone, a basin collects the groundwood pulp

The pulp is screened after this process to remove shives (over sized particles) and then thickened

Varieties of Stone groundwood pulp

Fine groundwood pulp

·         Low moisture content in the logs

·         Gentle pressing of the log in the grinding zone (low speed of the chain drives) leads to a lower load consumption

·         Grit size – small dia grit size

·         Less sharpening of the grindstone with small dia grit on the abrasive layer

·         Less sharpening of the grindstone

·         Higher consistency in the basin

·         High specific energy consumption
As a result, the shopper riegler value is high, low dewatering ability

Coarse groundwood pulp

·         Fresh wood high moisture content

·         Intense pressing of the log in the grinding zone – increased the load on grindstone

·         Grit size :usage of grind stone with large diameter grit

·         Sharp stone surface

·         Low consistency in the basin

·         Low specific energy consumption

·         Result in good dewatering ability – high shopper riegler

Consistency Meters - Papermachine Automation

Consistency Meters

Rotor designed consistency meters

The most common consistency meter found, the rotor design CM (Consistency meter) sits just outside of the stock flow stream. A deflector rotor pulls stock into the recess where the measurement device rotates at a constant speed. The stock gets thicker the torque on the motor to maintain that speed increases. The consistency can then be measured against the motor torque. This is known as a strain gauge. These types of measurement devices require a certain flow to function correctly and can measure consistencies of 1% - 10%.

unlike fixed blade consistency meters the rotor design is not affected by the variations in stock flows because the device creates its own flow from the deflection rotor onto the measurment device.

Fixed blade Consistency meters

Fixed blade CM work in the same way as the rotor design except the paddle is placed within the fiber flow stream. The fixed paddles moves with the fiber flow. The consistency increases in the pip, this in turn increases the force against the blade. The force is measured by the meter and calculated to a consistency. This is another instance of a strain gauge. 

The limitation with this type of measurement device is the stationary aspect. As stock flows past the paddle, fiber and rejects can stick/ build up reducing the accuracy of the device.
Variable flow within the pipe will alter the consistency measurment. A higher flow will add a higher force onto the consistency meter resulting in a higher measured consistency.

The major advantage of this type of meaurment is cost - usually customers purchase a fixed blade/ dynamic blade consistency measurment will the intention of replaying it with a better model.

Microwave Consistency meters

Microwave transmitters work on the principle that sending microwaves through water the waves travel at a certain speed. When fiber is introduces the microwaves move faster through the stream. The consistency can therefore be measured depending on the speed of the microwaves being sent and received by the meter. 

Using the calculation;   Velocity = C / sqrt(e)   

Where; C = Speed of light in a vacuum

     E = Dielectric constant of liquid (water)

These devices are more accurate than the rotor/ blade design. The microwave Transmitter also has no moving parts for the pulp to affect/ build up on like the blade transmitter.

The CM is not affected by the flow rate, colour, and brightness, like traditional microwave ovens they are highly affected by metals. these consistency meters are used within very clean pulp systems like the aproach flow because the likleyhood of metals entering the stream are very low. The microwave transmitter needs to be the same size as the pipe being used. Due to the expensive nature of these devices microwave transmitters are typically used on smaller pipe work or substituted for cheaper models. 

For more Info on Instrumentation within paper-making check out my other blog posts!

Level transmitters;
https://www.papermakingbible.co.uk/2018/04/process-level-indicators-papermachine.html

PID controllers;
https://www.papermakingbible.co.uk/2018/02/pid-control-loop-parameters.htm

Consistency Measurement - Technical Papermaking

Consistency Measurement


Testing the consistency of a stock is the same as consistency of water solution. Consistency is the term given to the amount of solid matter within a body of liquid. The higher the consistency the more solid matter is present within the same volume of liquid. Consistency is measured in percentage; it’s a percentage/ ratio of solid matter to water in a certain volume.


To find the consistency we need to test the amount of dry content within a set volume of water. For example if we wanted the consistency of 100ml of water, and tested 25 gram of dry solids the consistency would be about 25%.

To capture the solid content within a solution a filter paper is used. Firstly the filter paper is weighed at 0% moisture (previously oven dried) and recorded. The stock sample is weighed (1g = 1ml) and recorded. The weighed stock sample is filtered through a vacuum and rinsed making sure all of the solids from the sample are on the sheet. The filtered solids and the filter paper go into the oven to remove all of the remaining moisture.

Once the sample leaves the oven it is weighed and recorded. This formula is used to calculate the consistency below.

Consistency=  (Mass of Solids)/(Volume of Liquid)

We have to calculate the mass of the solids captured on the filter paper, this is calculated below;

Mass of Solids=Total dry weight-Filter paper weight

Here are a list of results that I took from measuring the consistencies of a pulp preparation plant's stock flows through two fractionators and Long fiber screens.